rockstrat says:
then when I have the chord that is the main tone in the progression that is the scale that I need to use for the song?
Hi There. As Doz said, the first chord isn't always indicative of the key. When you are trying to find the key for a chord progression, you basically have to figure out which key contains the greatest number of the chords you have in your progression, and that will be a pointer to the right key.
If you look at the pic I attached of the major keys, you can see that Em is included in alot of major keys - it could be C, G, D or Gflat major. The more chords you have in a progression, the easier key analysis gets (within reason).
For example... if you had a progression that was Em, Am, F - you'd probably be in the key of C, because the key of C is the only key that has all those chords in it.
(although you could also be in the key of Gflat, since in rock the diminished chords are sometimes played as if they are not diminished... but thats an unlikely key :)